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The Xindi in Season Two and More

the only episode that had anything to do with the xindi in Season Two of Enterprise was the season finally entitled 'The Expanse'.  It started it all, so it will be included in this episode database.  All other appearences of the xindi happen in Season Three so far, but more may appear later on... we don't know.

Also, there are only a few episodes that are NOT generally related to the xindi plot, here's the list.  They'll be in the synopsis section though:

Extinction

Impulse

 and North Star

P.S. Anomoly is relavent to the plot because of the sphere's appearences.

Synopsis:

The Expanse: When a probe from an unknown alien source unleashes a devastating assault upon Earth, Enterprise is recalled, then sent to search for the perpetrators.

The Xindi: Captain Archer and his crew set out to gain information about the mysterious and antagonistic Xindi race.

Anomoly: Enterprise starts experiencing effects of the spatial distortions pervading the Delphic Expanse, and falls victim to predatory aliens.

Extinction: On a mission to investigate an abandoned Xindi vessel on a jungle planet, Archer, Reed and Hoshi succumb to a virus that mutates them into a primal life form.

Rajiin: The NX-01 gets closer to a showdown with the Xindi when Captain Archer takes on an enigmatic passenger: a beautiful slave named Rajiin.

Impulse: When Enterprise responds to a distress call from a Vulcan ship stranded in the Delphic Expanse, Archer and his boarding team are attacked by insane zombie-like Vulcans.

Exile: A powerful telepath makes contact with Hoshi and offers to help Enterprise find the Xindi ... for a price.

The Shipment: Archer, Reed and Major Hayes infiltrate a Xindi-Sloth industrial colony to learn more about the weapon of mass destruction that will be used against Earth.

Twilight: A spatial distortion leaves Archer unable to form any new long-term memories. Years in the future, he wakes up one morning and is stunned to learn the outcome of the human-Xindi conflict.

North Star: When a settlement of humans living a 19th-century Western lifestyle is discovered on a Delphic Expanse planet, Archer and crew set out to learn how they got there.

Similitude: When Trip suffers a catastrophic injury, his only hope for survival is a transplant from a "mimetic simbiot" which Phlox grows from one of his exotic creatures.

Carpenter Street: Archer and T'Pol travel back in time to 2004 Detroit to stop a Xindi plot.

Chosen Realm: A group of religious zealots hijack Enterprise intending to use it against the enemies of their faith.

Proving Ground: An Andorian ship led by Commander Shran arrives in the Delphic Expanse to help Enterprise hone in on the Xindi superweapon.

Stratagem: Archer finds himself face-to-face with Degra, the designer of the Xindi superweapon, and tries to trick him into revealing its location.

Harbinger: Enterprise rescues a dying alien from a colossal spatial anomaly, and he refuses to reveal why he was there. Meanwhile, tensions between Reed and Hayes heat up as new training drills begin.

Doctor's Orders: The fate of Enterprise is in Dr. Phlox's hands as the rest of the crew must be induced into a coma in order to survive a trans-dimensional disturbance.

Hatchery: Enterprise finds a crashed Xindi-Insectoid ship containing an incubation chamber filled with Insectoid eggs. The crew must now decide whether to devote resources to save the offspring.

Azati Prime: Archer embarks on a suicide mission to destroy the Xindi's nearly completed planet-killing weapon.

Damage: While dissension among Xindi ranks festers, Enterprise tries to recover from a devastating attack.

The Forgotten: Two high-ranking Xindi offer to stop the launch of their superweapon if Archer can prove they've been manipulated. Meanwhile, the crew mourns their lost mates.

E2 (e-squared): An attempt to use a Xindi subspace corridor leads Enterprise to a bizarre encounter with another Starfleet ship.

The Council: Archer confronts the Xindi Council as T'pol and Major Hayes infiltrate an important sphere.

Countdown: plot is unknown so far.